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Biblioteca (s) : |
INIA Las Brujas. |
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Fecha : |
12/11/2015 |
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Actualizado : |
09/10/2019 |
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Tipo de producción científica : |
Artículos en Revistas Indexadas Internacionales |
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Autor : |
BESIL, N.; PÉREZ-PARADA, A.; CESIO, V.; VARELA, P.; RIVAS, F.; HEINZEN, H. |
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Afiliación : |
NATALIA BESIL, Universidad de la República (UdelaR)/ Centro Universitario Regional Noroeste, Salto (CENUR); Universidad de la República (UdelaR)/ Facultad de Química; ANDRÉS PÉREZ-PARADA, Universidad de la República (UdelaR)/ Facultad de Química; VERÓNICA CESIO, Universidad de la República (UdelaR)/ Facultad de Química; PABLO NICOLAS VARELA PESSOLANO, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; CARLOS FERNANDO RIVAS GRELA, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; HORACIO HEINZEN, Universidad de la República (UdelaR)/ Centro Universitario Regional Noroeste, Salto (CENUR); Universidad de la República (UdelaR)/ Facultad de Química. |
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Título : |
Degradation of imazalil, orthophenylphenol and pyrimethanil in Clementine mandarins under conventional postharvest industrial conditions at 4 °C. |
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Fecha de publicación : |
2015 |
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Fuente / Imprenta : |
Food Chemistry, 2016, v.194, p. 1132-1137. |
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ISSN : |
0308-8146 |
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DOI : |
10.1016/j.foodchem.2015.08.111 |
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Idioma : |
Inglés |
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Notas : |
Article history: Received 16 April 2015 / Received in revised form 25 August 2015 / Accepted 25 August 2015 / Available online 29 August 2015.
Chemical compounds studied in this article: Imazalil (PubChem CID: 37175) / Orthophenylphenol (PubChem CID: 7017) / Pyrimethanil (PubChem CID: 91650). |
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Contenido : |
ABSTRACT.
The degradation of the postharvest fungicides imazalil, orthophenylphenol, and pyrimethanil was studied on Clementine mandarins during packinghouse storage for a 28 day period at 4 C. Fruits to which orthophenylphenol was applied, were treated with imazalil and pyrimethanil at doses of 1000 and 2000 mg L1, using cascade application for the later and cascade and wax for the former. The decay of the three fungicides was evaluated using an in-house validated analytical procedure that includes the extraction and dispersive clean up of the samples followed by the GC?MS determination of the pesticide residues. The impact of fruit storage time on pesticide residues concentration was assessed. The residues
found for the different application technologies were always below the established Maximum Residue Limits by the Codex Alimentarius and the European Union (5 mg kg1 for imazalil, 7 and 8 mg kg1 for pyrimethanil, and 10 mg kg1 and 5 mg kg1 for orthophenylphenol). The fungicides dissipated differentially.
Pyrimethanil showed little degradation, if any, at both tested concentrations, but the half-life of imazalil on the fruit was 15?18 days, independent of the application technology. Orthophenylphenol dissipated with a half-life of 15 days. The initial imazalil residue found after cascade treatment was not significantly different between the doses studied (p < 0.5), whereas when the fungicide was included in wax as an emulsifiable concentrate the initial and final imazalil residues were significantly different.
Final residue levels after 28 days of storage were 0.12?0.24 mg kg1 for imazalil, 0.68 mg kg1 for 2-phenylphenol and 0.56 mg kg1 for pyrimethanil for all the evaluated treatments.
2015 Elsevier Ltd. All rights reserved. MenosABSTRACT.
The degradation of the postharvest fungicides imazalil, orthophenylphenol, and pyrimethanil was studied on Clementine mandarins during packinghouse storage for a 28 day period at 4 C. Fruits to which orthophenylphenol was applied, were treated with imazalil and pyrimethanil at doses of 1000 and 2000 mg L1, using cascade application for the later and cascade and wax for the former. The decay of the three fungicides was evaluated using an in-house validated analytical procedure that includes the extraction and dispersive clean up of the samples followed by the GC?MS determination of the pesticide residues. The impact of fruit storage time on pesticide residues concentration was assessed. The residues
found for the different application technologies were always below the established Maximum Residue Limits by the Codex Alimentarius and the European Union (5 mg kg1 for imazalil, 7 and 8 mg kg1 for pyrimethanil, and 10 mg kg1 and 5 mg kg1 for orthophenylphenol). The fungicides dissipated differentially.
Pyrimethanil showed little degradation, if any, at both tested concentrations, but the half-life of imazalil on the fruit was 15?18 days, independent of the application technology. Orthophenylphenol dissipated with a half-life of 15 days. The initial imazalil residue found after cascade treatment was not significantly different between the doses studied (p < 0.5), whereas when the fungicide was included in wax as an emulsifiable concentrate the initial and final imazali... Presentar Todo |
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Palabras claves : |
Degradation; Postharvest fungicides. |
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Thesagro : |
CITRUS; FUNGICIDAS; TECNICA POSTCOSECHA. |
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Asunto categoría : |
H20 Enfermedades de las plantas |
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Marc : |
LEADER 02850naa a2200277 a 4500
001 1053857
005 2019-10-09
008 2015 bl uuuu u00u1 u #d
022 $a0308-8146
024 7 $a10.1016/j.foodchem.2015.08.111$2DOI
100 1 $aBESIL, N.
245 $aDegradation of imazalil, orthophenylphenol and pyrimethanil in Clementine mandarins under conventional postharvest industrial conditions at 4 °C.
260 $c2015
500 $aArticle history: Received 16 April 2015 / Received in revised form 25 August 2015 / Accepted 25 August 2015 / Available online 29 August 2015. Chemical compounds studied in this article: Imazalil (PubChem CID: 37175) / Orthophenylphenol (PubChem CID: 7017) / Pyrimethanil (PubChem CID: 91650).
520 $aABSTRACT. The degradation of the postharvest fungicides imazalil, orthophenylphenol, and pyrimethanil was studied on Clementine mandarins during packinghouse storage for a 28 day period at 4 C. Fruits to which orthophenylphenol was applied, were treated with imazalil and pyrimethanil at doses of 1000 and 2000 mg L1, using cascade application for the later and cascade and wax for the former. The decay of the three fungicides was evaluated using an in-house validated analytical procedure that includes the extraction and dispersive clean up of the samples followed by the GC?MS determination of the pesticide residues. The impact of fruit storage time on pesticide residues concentration was assessed. The residues found for the different application technologies were always below the established Maximum Residue Limits by the Codex Alimentarius and the European Union (5 mg kg1 for imazalil, 7 and 8 mg kg1 for pyrimethanil, and 10 mg kg1 and 5 mg kg1 for orthophenylphenol). The fungicides dissipated differentially. Pyrimethanil showed little degradation, if any, at both tested concentrations, but the half-life of imazalil on the fruit was 15?18 days, independent of the application technology. Orthophenylphenol dissipated with a half-life of 15 days. The initial imazalil residue found after cascade treatment was not significantly different between the doses studied (p < 0.5), whereas when the fungicide was included in wax as an emulsifiable concentrate the initial and final imazalil residues were significantly different. Final residue levels after 28 days of storage were 0.12?0.24 mg kg1 for imazalil, 0.68 mg kg1 for 2-phenylphenol and 0.56 mg kg1 for pyrimethanil for all the evaluated treatments. 2015 Elsevier Ltd. All rights reserved.
650 $aCITRUS
650 $aFUNGICIDAS
650 $aTECNICA POSTCOSECHA
653 $aDegradation
653 $aPostharvest fungicides
700 1 $aPÉREZ-PARADA, A.
700 1 $aCESIO, V.
700 1 $aVARELA, P.
700 1 $aRIVAS, F.
700 1 $aHEINZEN, H.
773 $tFood Chemistry, 2016$gv.194, p. 1132-1137.
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INIA Las Brujas (LB) |
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| Acceso al texto completo restringido a Biblioteca INIA Las Brujas. Por información adicional contacte bibliolb@inia.org.uy. |
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Registro completo
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Biblioteca (s) : |
INIA Las Brujas. |
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Fecha actual : |
23/07/2021 |
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Actualizado : |
23/07/2021 |
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Tipo de producción científica : |
Artículos en Revistas Indexadas Internacionales |
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Circulación / Nivel : |
Internacional - -- |
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Autor : |
OLIVARO, C.; ESCOBAL, M.; DE SOUZA, G.; MEDEROS, A. |
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Afiliación : |
CRISTINA OLIVARO, Espacio de Ciencia y Tecnología Química, Centro Universitario Regional Noreste, Universidad de la República, Tacuarembó, Uruguay; MICAELA ESCOBAL, Espacio de Ciencia y Tecnología Química, Centro Universitario Regional Noreste, Universidad de la República, Tacuarembó, Uruguay; GUILLERMO DE SOUZA, Espacio de Ciencia y Tecnología Química, Centro Universitario Regional Noreste, Universidad de la República, Tacuarembó, Uruguay; AMERICA ESTHER MEDEROS SILVEIRA, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay. |
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Título : |
Chemical characterisation and in vitro anthelmintic activity of phenolic-rich extracts from the leaves and branches of Maytenus ilicifolia, a native plant from South America. |
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Complemento del título : |
Short Communication. |
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Fecha de publicación : |
2021 |
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Fuente / Imprenta : |
Natural Product Research, 2021. Doi: https://doi.org/10.1080/14786419.2021.1948844 |
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DOI : |
10.1080/14786419.2021.1948844 |
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Idioma : |
Inglés |
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Notas : |
Article history: Received 28 Mar 2021, Accepted 20 Jun 2021, Published online: 06 Jul 2021.
Correspondence: Cristina Olivaro, emai: cristina.olivaro@cut.edu.uy -
Supplemental data for this article can be accessed online at https://www.tandfonline.com/doi/suppl/10.1080/14786419.2021.1948844
This work was supported by the INIA under Grant INIA CL_40 and PEDECIBA. Instituto Nacional de Investigación Agropecuaria (INIA); Programa de Desarrollo de las Ciencias Básicas (PEDECIBA). |
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Contenido : |
ABSTRACT - Free (epi) catechin, quercetin, (epi) gallocatechin, flavonol glycosides and condensed tannins were identified according to their molecular mass, characteristic product ions and retention times in extracts obtained from leaves and branches of Maytenus ilicifolia (Congorosa) by mass spectrometry. The in vitro anthelmintic activity against cattle gastrointestinal nematodes of Congorosa extract was determined using the Egg Hatch Inhibition Assay. Additionally, commercial quercetin, gallocatechin and epicatechin were evaluated. Although total phenolics, total tannins and condensed tannins contents were lower in branches extract than in leaves extract, the EC50 were 0.065mg/mL and 0.890 mg/mL for branches and leaves extract, respectively. Moreover, the use of polyvinylpyrrolidone as a blocking agent of tannins, did not change significantly the EC50 for branches extract, but significantly changed for leaves extract. Quercetin and gallocatechin EC50 values were in the range 0.03–0.05 mg/mL and epicatechin showed 100% inhibition of the egg hatching process at 0.004mg/mL.
Copyright © 2021 Informa UK Limited, trading as Taylor & Francis Group |
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Palabras claves : |
Egg hatch inhibition assay; Mass spectrometry; Maytenus ilicifolia; Phenolic compounds; Ruminants anthelmintic activity. |
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Asunto categoría : |
L73 Enfermedades de los animales |
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Marc : |
LEADER 02502naa a2200241 a 4500
001 1062322
005 2021-07-23
008 2021 bl uuuu u00u1 u #d
024 7 $a10.1080/14786419.2021.1948844$2DOI
100 1 $aOLIVARO, C.
245 $aChemical characterisation and in vitro anthelmintic activity of phenolic-rich extracts from the leaves and branches of Maytenus ilicifolia, a native plant from South America.$h[electronic resource]
260 $c2021
500 $aArticle history: Received 28 Mar 2021, Accepted 20 Jun 2021, Published online: 06 Jul 2021. Correspondence: Cristina Olivaro, emai: cristina.olivaro@cut.edu.uy - Supplemental data for this article can be accessed online at https://www.tandfonline.com/doi/suppl/10.1080/14786419.2021.1948844 This work was supported by the INIA under Grant INIA CL_40 and PEDECIBA. Instituto Nacional de Investigación Agropecuaria (INIA); Programa de Desarrollo de las Ciencias Básicas (PEDECIBA).
520 $aABSTRACT - Free (epi) catechin, quercetin, (epi) gallocatechin, flavonol glycosides and condensed tannins were identified according to their molecular mass, characteristic product ions and retention times in extracts obtained from leaves and branches of Maytenus ilicifolia (Congorosa) by mass spectrometry. The in vitro anthelmintic activity against cattle gastrointestinal nematodes of Congorosa extract was determined using the Egg Hatch Inhibition Assay. Additionally, commercial quercetin, gallocatechin and epicatechin were evaluated. Although total phenolics, total tannins and condensed tannins contents were lower in branches extract than in leaves extract, the EC50 were 0.065mg/mL and 0.890 mg/mL for branches and leaves extract, respectively. Moreover, the use of polyvinylpyrrolidone as a blocking agent of tannins, did not change significantly the EC50 for branches extract, but significantly changed for leaves extract. Quercetin and gallocatechin EC50 values were in the range 0.03–0.05 mg/mL and epicatechin showed 100% inhibition of the egg hatching process at 0.004mg/mL. Copyright © 2021 Informa UK Limited, trading as Taylor & Francis Group
653 $aEgg hatch inhibition assay
653 $aMass spectrometry
653 $aMaytenus ilicifolia
653 $aPhenolic compounds
653 $aRuminants anthelmintic activity
700 1 $aESCOBAL, M.
700 1 $aDE SOUZA, G.
700 1 $aMEDEROS, A.
773 $tNatural Product Research, 2021. Doi: https://doi.org/10.1080/14786419.2021.1948844
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