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Biblioteca (s) : |
INIA Las Brujas. |
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Fecha : |
12/11/2015 |
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Actualizado : |
09/10/2019 |
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Tipo de producción científica : |
Artículos en Revistas Indexadas Internacionales |
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Autor : |
BESIL, N.; PÉREZ-PARADA, A.; CESIO, V.; VARELA, P.; RIVAS, F.; HEINZEN, H. |
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Afiliación : |
NATALIA BESIL, Universidad de la República (UdelaR)/ Centro Universitario Regional Noroeste, Salto (CENUR); Universidad de la República (UdelaR)/ Facultad de Química; ANDRÉS PÉREZ-PARADA, Universidad de la República (UdelaR)/ Facultad de Química; VERÓNICA CESIO, Universidad de la República (UdelaR)/ Facultad de Química; PABLO NICOLAS VARELA PESSOLANO, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; CARLOS FERNANDO RIVAS GRELA, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; HORACIO HEINZEN, Universidad de la República (UdelaR)/ Centro Universitario Regional Noroeste, Salto (CENUR); Universidad de la República (UdelaR)/ Facultad de Química. |
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Título : |
Degradation of imazalil, orthophenylphenol and pyrimethanil in Clementine mandarins under conventional postharvest industrial conditions at 4 °C. |
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Fecha de publicación : |
2015 |
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Fuente / Imprenta : |
Food Chemistry, 2016, v.194, p. 1132-1137. |
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ISSN : |
0308-8146 |
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DOI : |
10.1016/j.foodchem.2015.08.111 |
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Idioma : |
Inglés |
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Notas : |
Article history: Received 16 April 2015 / Received in revised form 25 August 2015 / Accepted 25 August 2015 / Available online 29 August 2015.
Chemical compounds studied in this article: Imazalil (PubChem CID: 37175) / Orthophenylphenol (PubChem CID: 7017) / Pyrimethanil (PubChem CID: 91650). |
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Contenido : |
ABSTRACT.
The degradation of the postharvest fungicides imazalil, orthophenylphenol, and pyrimethanil was studied on Clementine mandarins during packinghouse storage for a 28 day period at 4 C. Fruits to which orthophenylphenol was applied, were treated with imazalil and pyrimethanil at doses of 1000 and 2000 mg L1, using cascade application for the later and cascade and wax for the former. The decay of the three fungicides was evaluated using an in-house validated analytical procedure that includes the extraction and dispersive clean up of the samples followed by the GC?MS determination of the pesticide residues. The impact of fruit storage time on pesticide residues concentration was assessed. The residues
found for the different application technologies were always below the established Maximum Residue Limits by the Codex Alimentarius and the European Union (5 mg kg1 for imazalil, 7 and 8 mg kg1 for pyrimethanil, and 10 mg kg1 and 5 mg kg1 for orthophenylphenol). The fungicides dissipated differentially.
Pyrimethanil showed little degradation, if any, at both tested concentrations, but the half-life of imazalil on the fruit was 15?18 days, independent of the application technology. Orthophenylphenol dissipated with a half-life of 15 days. The initial imazalil residue found after cascade treatment was not significantly different between the doses studied (p < 0.5), whereas when the fungicide was included in wax as an emulsifiable concentrate the initial and final imazalil residues were significantly different.
Final residue levels after 28 days of storage were 0.12?0.24 mg kg1 for imazalil, 0.68 mg kg1 for 2-phenylphenol and 0.56 mg kg1 for pyrimethanil for all the evaluated treatments.
2015 Elsevier Ltd. All rights reserved. MenosABSTRACT.
The degradation of the postharvest fungicides imazalil, orthophenylphenol, and pyrimethanil was studied on Clementine mandarins during packinghouse storage for a 28 day period at 4 C. Fruits to which orthophenylphenol was applied, were treated with imazalil and pyrimethanil at doses of 1000 and 2000 mg L1, using cascade application for the later and cascade and wax for the former. The decay of the three fungicides was evaluated using an in-house validated analytical procedure that includes the extraction and dispersive clean up of the samples followed by the GC?MS determination of the pesticide residues. The impact of fruit storage time on pesticide residues concentration was assessed. The residues
found for the different application technologies were always below the established Maximum Residue Limits by the Codex Alimentarius and the European Union (5 mg kg1 for imazalil, 7 and 8 mg kg1 for pyrimethanil, and 10 mg kg1 and 5 mg kg1 for orthophenylphenol). The fungicides dissipated differentially.
Pyrimethanil showed little degradation, if any, at both tested concentrations, but the half-life of imazalil on the fruit was 15?18 days, independent of the application technology. Orthophenylphenol dissipated with a half-life of 15 days. The initial imazalil residue found after cascade treatment was not significantly different between the doses studied (p < 0.5), whereas when the fungicide was included in wax as an emulsifiable concentrate the initial and final imazali... Presentar Todo |
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Palabras claves : |
Degradation; Postharvest fungicides. |
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Thesagro : |
CITRUS; FUNGICIDAS; TECNICA POSTCOSECHA. |
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Asunto categoría : |
H20 Enfermedades de las plantas |
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Marc : |
LEADER 02850naa a2200277 a 4500
001 1053857
005 2019-10-09
008 2015 bl uuuu u00u1 u #d
022 $a0308-8146
024 7 $a10.1016/j.foodchem.2015.08.111$2DOI
100 1 $aBESIL, N.
245 $aDegradation of imazalil, orthophenylphenol and pyrimethanil in Clementine mandarins under conventional postharvest industrial conditions at 4 °C.
260 $c2015
500 $aArticle history: Received 16 April 2015 / Received in revised form 25 August 2015 / Accepted 25 August 2015 / Available online 29 August 2015. Chemical compounds studied in this article: Imazalil (PubChem CID: 37175) / Orthophenylphenol (PubChem CID: 7017) / Pyrimethanil (PubChem CID: 91650).
520 $aABSTRACT. The degradation of the postharvest fungicides imazalil, orthophenylphenol, and pyrimethanil was studied on Clementine mandarins during packinghouse storage for a 28 day period at 4 C. Fruits to which orthophenylphenol was applied, were treated with imazalil and pyrimethanil at doses of 1000 and 2000 mg L1, using cascade application for the later and cascade and wax for the former. The decay of the three fungicides was evaluated using an in-house validated analytical procedure that includes the extraction and dispersive clean up of the samples followed by the GC?MS determination of the pesticide residues. The impact of fruit storage time on pesticide residues concentration was assessed. The residues found for the different application technologies were always below the established Maximum Residue Limits by the Codex Alimentarius and the European Union (5 mg kg1 for imazalil, 7 and 8 mg kg1 for pyrimethanil, and 10 mg kg1 and 5 mg kg1 for orthophenylphenol). The fungicides dissipated differentially. Pyrimethanil showed little degradation, if any, at both tested concentrations, but the half-life of imazalil on the fruit was 15?18 days, independent of the application technology. Orthophenylphenol dissipated with a half-life of 15 days. The initial imazalil residue found after cascade treatment was not significantly different between the doses studied (p < 0.5), whereas when the fungicide was included in wax as an emulsifiable concentrate the initial and final imazalil residues were significantly different. Final residue levels after 28 days of storage were 0.12?0.24 mg kg1 for imazalil, 0.68 mg kg1 for 2-phenylphenol and 0.56 mg kg1 for pyrimethanil for all the evaluated treatments. 2015 Elsevier Ltd. All rights reserved.
650 $aCITRUS
650 $aFUNGICIDAS
650 $aTECNICA POSTCOSECHA
653 $aDegradation
653 $aPostharvest fungicides
700 1 $aPÉREZ-PARADA, A.
700 1 $aCESIO, V.
700 1 $aVARELA, P.
700 1 $aRIVAS, F.
700 1 $aHEINZEN, H.
773 $tFood Chemistry, 2016$gv.194, p. 1132-1137.
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INIA Las Brujas (LB) |
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| Acceso al texto completo restringido a Biblioteca INIA La Estanzuela. Por información adicional contacte bib_le@inia.org.uy. |
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Registro completo
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Biblioteca (s) : |
INIA La Estanzuela. |
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Fecha actual : |
03/01/2019 |
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Actualizado : |
11/11/2019 |
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Tipo de producción científica : |
Artículos en Revistas Indexadas Internacionales |
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Circulación / Nivel : |
Internacional - -- |
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Autor : |
GARMENDIA, G.; PATTARINO, L.; NEGRIN, C.; MARTÍNEZ-SILVEIRA, A.; PEREYRA, S.; WARD, T.J.; VERO, S. |
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Afiliación : |
GABRIELA GARMENDIA, Área Microbiología, Departamento de Biociencias, Facultad de Química, Universidad de la República, General Flores 2124, 11800, Montevideo, Uruguay.; LUCIANA PATTARINO, Área Microbiología, Departamento de Biociencias, Facultad de Química, Universidad de la República, Montevideo, Uruguay.; CAMILA NEGRIN TORRES, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay.Área Microbiología, Departamento de Biociencias, Facultad de Química, Universidad de la República, Montevideo, Uruguay.; ADALGISA MARTÍNEZ-SILVEIRA, Área Microbiología, Departamento de Biociencias, Facultad de Química, Universidad de la República, Montevideo, Uruguay.; SILVIA ANTONIA PEREYRA CORREA, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; TODD J. WARD, Mycotoxin Prevention and Applied Microbiology, USDA-ARS, 1815 N, University St.Peoria, IL, 61604, USA.; SILVANA VERO, Área Microbiología, Departamento de Biociencias, Facultad de Química, Universidad de la República, Montevideo, Uruguay. |
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Título : |
Species composition, toxigenic potential and aggressiveness of Fusarium isolates causing Head Blight of barley in Uruguay. |
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Fecha de publicación : |
2018 |
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Fuente / Imprenta : |
Food Microbiology, v. 76, December 2018, p. 426-433. |
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ISSN : |
1095-9998 |
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DOI : |
10.1016/j.fm.2018.07.005 |
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Idioma : |
Inglés |
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Notas : |
Article history: Received 22 September 2017// Revised 14 March 2018//Accepted 12 July 2018// Available online 17 July 2018. |
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Contenido : |
ABSTRACT:Fusarium Head Blight (FHB) is a major constraint to barley production that substantially reduces yield and grain quality. FHB is also a major food safety concern because FHB pathogens contaminate grain with trichothecenes and other mycotoxins. DNA sequence-based analyses and in-vitro toxin assessments were used to characterize the species and trichothecene chemotype composition of FHB pathogens on barley in Uruguay. F. graminearum was the dominant species (89.7%), and three other members of the F. graminearum species complex (FGSC) were identified as FHB pathogens of barley in Uruguay for the first time. Other minor contributors to FHB species diversity included F. poae, F. avenaceum, F. pseudograminearum and an unnamed species from the F. incarnatumequiseti species complex (FIESC). Most isolates (89.7%) had the 15-acetyldeoxynivalenol (15-ADON) trichothecene type. However, the results expanded the known area of occurrence within Uruguay for the nivalenol (NIV) toxin type, which was observed among isolates from three species of the FGSC, F. pseudograminearum, and F. poae. Isolates with the 3-acetyldeoxynivalenol (3-ADON) or NX-2 toxin types were not observed, although a previously published multilocus genotyping assay was updated to identify NX-2 strains. Analyses of population structure and comparisons with FHB isolates from wheat in Uruguay indicated that F. graminearum constitutes a single genetic population with no evidence of population differentiation related to the sampled hosts. Inter and intraspecific differences were observed in aggressiveness toward four barley genotypes with different levels of resistance to FHB, and in general nivalenol producers were the least aggressive isolates. Sensitivity to metconazole was approximately 10 times higher than was detected for tebuconazole. This is the first report regarding tebuconazole and metconazole sensitivity for Fusarium species causing FHB in barley in Uruguay, and constitutes an important starting point for monitoring temporal or spatial changes in FGSC sensitivity, which is critical to define FHB management practices. MenosABSTRACT:Fusarium Head Blight (FHB) is a major constraint to barley production that substantially reduces yield and grain quality. FHB is also a major food safety concern because FHB pathogens contaminate grain with trichothecenes and other mycotoxins. DNA sequence-based analyses and in-vitro toxin assessments were used to characterize the species and trichothecene chemotype composition of FHB pathogens on barley in Uruguay. F. graminearum was the dominant species (89.7%), and three other members of the F. graminearum species complex (FGSC) were identified as FHB pathogens of barley in Uruguay for the first time. Other minor contributors to FHB species diversity included F. poae, F. avenaceum, F. pseudograminearum and an unnamed species from the F. incarnatumequiseti species complex (FIESC). Most isolates (89.7%) had the 15-acetyldeoxynivalenol (15-ADON) trichothecene type. However, the results expanded the known area of occurrence within Uruguay for the nivalenol (NIV) toxin type, which was observed among isolates from three species of the FGSC, F. pseudograminearum, and F. poae. Isolates with the 3-acetyldeoxynivalenol (3-ADON) or NX-2 toxin types were not observed, although a previously published multilocus genotyping assay was updated to identify NX-2 strains. Analyses of population structure and comparisons with FHB isolates from wheat in Uruguay indicated that F. graminearum constitutes a single genetic population with no evidence of population differentiation related ... Presentar Todo |
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Palabras claves : |
BARLEY; MYCOTOXINS. |
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Thesagro : |
CEBADA; FUSARIUM; MICOTOXINAS. |
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Asunto categoría : |
H20 Enfermedades de las plantas |
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Marc : |
LEADER 03057naa a2200289 a 4500
001 1059407
005 2019-11-11
008 2018 bl uuuu u00u1 u #d
022 $a1095-9998
024 7 $a10.1016/j.fm.2018.07.005$2DOI
100 1 $aGARMENDIA, G.
245 $aSpecies composition, toxigenic potential and aggressiveness of Fusarium isolates causing Head Blight of barley in Uruguay.$h[electronic resource]
260 $c2018
500 $aArticle history: Received 22 September 2017// Revised 14 March 2018//Accepted 12 July 2018// Available online 17 July 2018.
520 $aABSTRACT:Fusarium Head Blight (FHB) is a major constraint to barley production that substantially reduces yield and grain quality. FHB is also a major food safety concern because FHB pathogens contaminate grain with trichothecenes and other mycotoxins. DNA sequence-based analyses and in-vitro toxin assessments were used to characterize the species and trichothecene chemotype composition of FHB pathogens on barley in Uruguay. F. graminearum was the dominant species (89.7%), and three other members of the F. graminearum species complex (FGSC) were identified as FHB pathogens of barley in Uruguay for the first time. Other minor contributors to FHB species diversity included F. poae, F. avenaceum, F. pseudograminearum and an unnamed species from the F. incarnatumequiseti species complex (FIESC). Most isolates (89.7%) had the 15-acetyldeoxynivalenol (15-ADON) trichothecene type. However, the results expanded the known area of occurrence within Uruguay for the nivalenol (NIV) toxin type, which was observed among isolates from three species of the FGSC, F. pseudograminearum, and F. poae. Isolates with the 3-acetyldeoxynivalenol (3-ADON) or NX-2 toxin types were not observed, although a previously published multilocus genotyping assay was updated to identify NX-2 strains. Analyses of population structure and comparisons with FHB isolates from wheat in Uruguay indicated that F. graminearum constitutes a single genetic population with no evidence of population differentiation related to the sampled hosts. Inter and intraspecific differences were observed in aggressiveness toward four barley genotypes with different levels of resistance to FHB, and in general nivalenol producers were the least aggressive isolates. Sensitivity to metconazole was approximately 10 times higher than was detected for tebuconazole. This is the first report regarding tebuconazole and metconazole sensitivity for Fusarium species causing FHB in barley in Uruguay, and constitutes an important starting point for monitoring temporal or spatial changes in FGSC sensitivity, which is critical to define FHB management practices.
650 $aCEBADA
650 $aFUSARIUM
650 $aMICOTOXINAS
653 $aBARLEY
653 $aMYCOTOXINS
700 1 $aPATTARINO, L.
700 1 $aNEGRIN, C.
700 1 $aMARTÍNEZ-SILVEIRA, A.
700 1 $aPEREYRA, S.
700 1 $aWARD, T.J.
700 1 $aVERO, S.
773 $tFood Microbiology$gv. 76, December 2018, p. 426-433.
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